In metallurgy, stainless steel, also known as inox steel or inox from French “inoxydable”, is a steel alloy with a minimum of 10.5% chromium content by mass.
Stainless steel does not readily corrode, rust or stain with water as ordinary steel does, but despite the name it is not fully stain-proof, most notably under low-oxygen, high-salinity, or poor-circulation environments.[2] There are different grades and surface finishes of stainless steel to suit the environment the alloy must endure. Stainless steel is used where both the properties of steel and resistance to corrosion are required.
High oxidation resistance in air at ambient temperature is normally achieved with additions of a minimum of 13% (by weight) chromium, and up to 26% is used for harsh environments. The chromium forms a passivation layer of chromium(III) oxide (Cr2O3) when exposed to oxygen. The layer is too thin to be visible, and the metal remains lustrous and smooth. The layer is impervious to water and air, protecting the metal beneath, and this layer quickly reforms when the surface is scratched. This phenomenon is called passivation and is seen in other metals, such as aluminium and titanium. Corrosion resistance can be adversely affected if the component is used in a non-oxygenated environment, a typical example being underwater keel bolts buried in timber.
Stainless steel is generally highly resistant to attack from acids, but this quality depends on the kind and concentration of the acid, the surrounding temperature, and the type of steel. Type 304 is resistant to sulfuric acid at room temperature, even in high concentrations, but type 316 and 317 are only resistant at low concentrations. All types of stainless steel resist attack from phosphoric acid, 316 and 317 more so than 304; and Types 304L and 430 have been successfully used with nitric acid. Hydrochloric acid will damage any kind of stainless steel, and should be avoided.
The 300 series of stainless steel grades is unaffected by any of the weak bases such as ammonium hydroxide, even in high concentrations and at high temperatures. The same grades of stainless exposed to stronger bases such as sodium hydroxide at high concentrations and high temperatures will likely experience some etching and cracking, especially with solutions containing chlorides.
Types 316 and 317 are both useful for storing and handling acetic acid, especially in solutions where it is combined with formic acid and when aeration is not present (oxygen helps protect stainless steel under such conditions), though 317 provides the greatest level of resistance to corrosion. Type 304 is also commonly used with formic acid though it will tend to discolor the solution. All grades resist damage from aldehydes and amines, though in the latter case grade 316 is preferable to 304; cellulose acetate will damage 304 unless the temperature is kept low. Fats and fatty acids only affect grade 304 at temperatures above 150 °C (302 °F), and grade 316 above 260 °C (500 °F), while 317 is unaffected at all temperatures. Type 316L is required for processing of urea.
“Similarly to steel, stainless steel is a relatively poor conductor of electricity, with a few percent of the electrical conductivity of copper. ” Ferritic and martensitic stainless steels are magnetic. Austenitic stainless steels are non-magnetic.
There are different types of stainless steels: when nickel is added, for instance, the austenite structure of iron is stabilized. This crystal structure makes such steels virtually non-magnetic and less brittle at low temperatures. For greater hardness and strength, more carbon is added. With proper heat treatment, these steels are used for such products as razor blades, cutlery, and tools.
A2-70, A4-70, A4-80, SS 304, SS 316, SS 316Ti, SS 317L, SS 321 etc are most common Stainless Steel Grade Fasteners Manufactured at TorqBolt Inc. Hex Bolt, Heavy Hex Bolts, Stud Bolts, Machine Bolts, Socket Cap Screws, Grub Screws, Hex Nut, Heavy Hex Nuts, Lock Nuts, Plain & Spring Washers are come common Stainless Steel Fastener Products.
Austenitic, or 200 and 300 series, stainless steels have an austenitic crystalline structure, which is a face-centered cubic crystal structure. Austenite steels make up over 70% of total stainless steel production. They contain a maximum of 0.15% carbon, a minimum of 16% chromium and sufficient nickel and/or manganese to retain an austenitic structure at all temperatures from the cryogenic region to the melting point of the alloy.
200 Series—austenitic chromium-nickel-manganese alloys. Type 201 is hardenable through cold working; Type 202 is a general purpose stainless steel. Decreasing nickel content and increasing manganese results in weak corrosion resistance.
300 Series—The most widely used austenite steel is the 304, also known as 18/8 for its composition of 18% chromium and 8% nickel. 304 may be the 316 grade, also called marine grade, stainless, used primarily for its increased resistance to corrosion. A typical composition of 18% referred to as A2 stainless (not to be confused with A2 grade steel, also named Tool steel, a steel). The second most common austenite steel is chromium and 10% nickel, commonly known as 18/10 stainless, is often used in cutlery and high-quality cookware. 18/0 is also available.
Superaustenitic stainless steels, such as alloy AL-6XN and 254SMO, exhibit great resistance to chloride pitting and crevice corrosion because of high molybdenum content (>6%) and nitrogen additions, and the higher nickel content ensures better resistance to stress-corrosion cracking versus the 300 series. The higher alloy content of superaustenitic steels makes them more expensive. Other steels can offer similar performance at lower cost and are preferred in certain applications, for example ASTM A387 is used in pressure vessels but is a low-alloy carbon steel with a chromium content of 0.5% to 9%. Low-carbon versions, for example 316L or 304L, are used to avoid corrosion problems caused by welding Grade 316LVM is preferred where biocompatibility is required (such as body implants and piercings).[24] The “L” means that the carbon content of the alloy is below 0.03%, which reduces the sensitization effect (precipitation of chromium carbides at grain boundaries) caused by the high temperatures involved in welding.
Ferritic stainless steels generally have better engineering properties than austenitic grades, but have reduced corrosion resistance, because of the lower chromium and nickel content. They are also usually less expensive. They contain between 10.5% and 27% chromium and very little nickel, Common ferritic grades include 18Cr-2Mo, 26Cr-1Mo, 29Cr-4Mo, and 29Cr-4Mo-2Ni. These alloys can be degraded by the presence of \ sigma chromium, an intermetallic phase which can precipitate upon welding.
Martensitic stainless steels are not as corrosion-resistant as the other two classes but are extremely strong and tough, as well as highly machinable, and can be hardened by heat treatment. Martensitic stainless steel contains chromium (12–14%), molybdenum (0.2–1%) nickel (less than 2%), and carbon (about 0.1–1%) (giving it more hardness but making the material a bit more brittle). It is quenched and . magnetic
Precipitation-hardening martensitic stainless steels have corrosion resistance comparable to austenitic varieties, but can be precipitation hardened to even higher strengths than the other martensitic grades. The most common, 17-4PH, uses about 17% chromium and 4% nickel.
Maintenance during installation
The quality of installation affects the durability and life-time of stainless steel.[18] Therefore it is important to make sure stainless steel is in good condition before installation. Normally, a quick cleaning is enough for installation in most cases. However, if surface contamination is present, more attention is required. In addition, an extremely high standard of cleanliness may be required for stainless steel applied used in the fields of aerospace, pharmaceuticals, and food handling.
There are different types of stainless steels: when nickel is added, for instance, the austenite structure of iron is stabilized. This crystal structure makes such steels virtually non-magnetic and less brittle at low temperatures. For greater hardness and strength, more carbon is added. With proper heat treatment, these steels are used for such products as razor blades, cutlery, and tools.
The quality of installation affects the durability and life-time of stainless steel.[18] Therefore it is important to make sure stainless steel is in good condition before installation. Normally, a quick cleaning is enough for installation in most cases. However, if surface contamination is present, more attention is required. In addition, an extremely high standard of cleanliness may be required for stainless steel applied used in the fields of aerospace, pharmaceuticals, and food handling.
Stainless steel’s resistance to corrosion and staining, low maintenance and familiar lustre make it an ideal material for many applications. There are over 150 grades of stainless steel, of which fifteen are most commonly used. The alloy is milled into coils, sheets, plates, bars, wire, and tubing to be used in cookware, cutlery, household hardware, surgical instruments, major appliances, industrial equipment (for example, in sugar refineries) and as an automotive and aerospace structural alloy and construction material in large buildings. Storage tanks and tankers used to transport orange juice and other food are often made of stainless steel, because of its corrosion resistance. This also influences its use in commercial kitchens and food processing plants, as it can be steam-cleaned and sterilized and does not need paint or other surface finishes.
